1990
DOI: 10.1002/pen.760302204
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Detergent assisted stress cracking in low density polyethylene

Abstract: Igepal assisted environmental stress cracking (ESC) of LDPE has shown three characteristic regions with increasing crack driving force: Region I‐crack speed and craze length increased. Region II‐crack speed and duplex plastic zone length were constant, and Region Ill‐crack speed decreased while the deformation zone length increased. The activation energies for the three regions were 100, 23, 20 kJ/mole, respectively. The proposed rate controlling processes of ESC for the LDPE/Igepal system are: Region 1 is con… Show more

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Cited by 12 publications
(6 citation statements)
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References 25 publications
(18 reference statements)
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“…From the intersection of the air and environment branches, critical interaction times * and critical crack growth rates ̇ * were evaluated. These parameters, previously observed in (Chang and Donovan, 1990;Ward et al, 1991;Ayyer, Hiltner and Baer, 2008;Andena et al, 2013;Kamaludin et al, 2017), reveal if a given environment will influence the fracture behaviour of a polymer. As a matter of fact, Environmental Stress Cracking will occur under conditions of or corresponding to fracture times that are longer than * and propagation rates lower than ̇ * .…”
Section: Resultsmentioning
confidence: 56%
“…From the intersection of the air and environment branches, critical interaction times * and critical crack growth rates ̇ * were evaluated. These parameters, previously observed in (Chang and Donovan, 1990;Ward et al, 1991;Ayyer, Hiltner and Baer, 2008;Andena et al, 2013;Kamaludin et al, 2017), reveal if a given environment will influence the fracture behaviour of a polymer. As a matter of fact, Environmental Stress Cracking will occur under conditions of or corresponding to fracture times that are longer than * and propagation rates lower than ̇ * .…”
Section: Resultsmentioning
confidence: 56%
“…The SCR behavior is practically the same in water and air incubation environments. The acceleration effect of the 10% Igepal on the SCR is expected and well documented (4,5). On the other hand, the similarity of the SCR in water and air environments is different than the results obtained from compression molded plaques of a HDPE corrugated pipe (6).…”
Section: Discussion Of Resultsmentioning
confidence: 88%
“…On the other hand, when the rate of permeation is slow compared with crack growth rate, region B tends to dominate. I t has been pointed out that in some cases, the crack propagation behavior of polymers by ESC can be understood by the linear fracture mechanics (15,16) using the parameters such as stress intensity factor or strain energy release rate. Although the authors attempted to apply fracture mechanics to crack propagation behavior found in this study, it was not successful because of the fact that in some cases different crack propagation and crack arrest mechanisms appeared alternately at the crack tip, which was not clearly related to the stress intensity factor at the crack tip.…”
Section: Dependence Of Crack Propagation Behavior On Temperature and mentioning
confidence: 99%