Three dierent kinds of polymer lms, poly (divinylbenzene), poly (ethylene glycol dimethacrylate) and poly (vinyl alcohol), containing M -type hexagonal barium ferrites (BaFe12O19) were synthesized on glass substrates by using surface polymerization method. The structural properties were characterized by X-ray diraction and atomic force microscopy. X-ray diraction patterns show that polymer lms have a polycrystalline structure. The magnetic measurement of polymer lms were examined at room temperature using vibrating sample magnetometer and magnetic force microscopy, respectively. The magnetic measurements indicate that P(VA)-BF lms exhibit higher saturation magnetization and coercive eld than P(EGDMA)-BF and P(DVB)-BF lms.