The development of high performance lubricants has been driven by increasingly growing industrial demands and environmental concerns.H erein, we demonstrate oilsoluble polymer brush-grafted inorganic nanoparticles (hairy NPs) as highly effective lubricant additives for friction and wear reduction. As eries of oil-miscible poly(lauryl methacrylate) brush-grafted silica and titania NPs were synthesized by surface-initiated atom transfer radical polymerization. These hairy NPs showed exceptional stability in poly(alphaolefin) (PAO)base oil;nochange in transparency was observed after being kept at À20, 22, and 100 8 8Cf or ! 55 days.H igh-contact stress ball-on-flat reciprocating sliding tribological tests at 100 8 8Cshowed that addition of 1wt% of hairy NPs into PAO led to significant reductions in coefficient of friction (up to % 40 %) and wear volume (up to % 90 %). The excellent lubricating properties of hairy NPs were further elucidated by the characterization of the tribofilm formed on the flat. These hairy NPs represent anew type of lubricating oil additives with high efficiency in friction and wear reduction.