Design of renewable poly(amidoamine)/hemicellulose hydrogels for heavy metal adsorption

Ferrari, Elena; Ranucci, Elisabetta; Edlund, Ulrica; Albertsson, Ann‐Christine

doi:10.1002/app.41695

Cited by 35 publications

(8 citation statements)

References 37 publications

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“…Also, mechanical treatment in water can lead to extraction of material from wood. Much interest has been focused on the materials obtained in water solution after mechanical pulping, which have been shown to be rich in glucomannans and also some lignins . As described above, wood is a cross-linked structure, and direct extraction from wood without any pretreatment or breaking of covalent bonds is difficult.…”

Section: Wood Structure and Chemistrymentioning

confidence: 99%

Wood-Derived Materials for Green Electronics, Biological Devices, and Energy Applications

et al. 2016

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With the arising of global climate change and resource shortage, in recent years, increased attention has been paid to environmentally friendly materials. Trees are sustainable and renewable materials, which give us shelter and oxygen and remove carbon dioxide from the atmosphere. Trees are a primary resource that human society depends upon every day, for example, homes, heating, furniture, and aircraft. Wood from trees gives us paper, cardboard, and medical supplies, thus impacting our homes, school, work, and play. All of the above-mentioned applications have been well developed over the past thousands of years. However, trees and wood have much more to offer us as advanced materials, impacting emerging high-tech fields, such as bioengineering, flexible electronics, and clean energy. Wood naturally has a hierarchical structure, composed of well-oriented microfibers and tracheids for water, ion, and oxygen transportation during metabolism. At higher magnification, the walls of fiber cells have an interesting morphology-a distinctly mesoporous structure. Moreover, the walls of fiber cells are composed of thousands of fibers (or macrofibrils) oriented in a similar angle. Nanofibrils and nanocrystals can be further liberated from macrofibrils by mechanical, chemical, and enzymatic methods. The obtained nanocellulose has unique optical, mechanical, and barrier properties and is an excellent candidate for chemical modification and reconfiguration. Wood is naturally a composite material, comprised of cellulose, hemicellulose, and lignin. Wood is sustainable, earth abundant, strong, biodegradable, biocompatible, and chemically accessible for modification; more importantly, multiscale natural fibers from wood have unique optical properties applicable to different kinds of optoelectronics and photonic devices. Today, the materials derived from wood are ready to be explored for applications in new technology areas, such as electronics, biomedical devices, and energy. The goal of this study is to review the fundamental structures and chemistries of wood and wood-derived materials, which are essential for a wide range of existing and new enabling technologies. The scope of the review covers multiscale materials and assemblies of cellulose, hemicellulose, and lignin as well as other biomaterials derived from wood, in regard to their major emerging applications. Structure-properties-application relationships will be investigated in detail. Understanding the fundamental properties of these structures is crucial for designing and manufacturing products for emerging applications. Today, a more holistic understanding of the interplay between the structure, chemistry, and performance of wood and wood-derived materials is advancing historical applications of these materials. This new level of understanding also enables a myriad of new and exciting applications, which motivate this review. There are excellent reviews already on the classical topic of woody materials, and some recent reviews also cover new understanding of these mate...

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Section: Wood Structure and Chemistrymentioning

confidence: 99%

Wood-Derived Materials for Green Electronics, Biological Devices, and Energy Applications

et al. 2016

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“…mentation. Hemicellulose was used as an adsorption material or matrix of acrylamide in previous studies [52,53].…”

Section: Potentially Harmful Substances-adsorption Capacity Of Hpidf/f-hpidfmentioning

confidence: 99%

“…Then we speculated that the decrease of AAC of F-HPIDF still came from the degradation of hemicellulose, although the specific surface area of F-HPIDF increased with the progress of fermentation. Hemicellulose was used as an adsorption material or matrix of acrylamide in previous studies [52,53].…”

Section: Potentially Harmful Substances-adsorption Capacity Of Hpidf/f-hpidfmentioning

confidence: 99%

Changes of High-Purity Insoluble Fiber from Soybean Dregs (Okara) after Being Fermented by Colonic Flora and Its Adsorption Capacity

Lyu

Wang

Zhang

et al. 2021

Foods

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In order to explore the changes and properties of high-purity insoluble dietary fiber from okara (HPIDF) after entering the colon and be fermented by colonic flora, fermented high-purity insoluble dietary fiber (F-HPIDF) was obtained by simulated fermentation in vitro by HPIDF and colonic flora from C57BL/6 mice. For exploring the differences of HPIDF and F-HPIDF, the changes of structure (SEM. FTIR, XRD, particle size, specific surface area, monosaccharide composition) and adsorption properties (water, oil, heavy metal irons, harmful substances) of HPIDF/F-HPIDF were explored. The results showed that F-HPIDF had a higher water-holding capacity (19.17 g/g), water-swelling capacity (24.83 mL/g), heavy metals-adsorption capacity (Cd2+: 1.82 μmol/g; Pb2+: 1.91 μmol/g; Zn2+: 1.30 μmol/g; Cu2+: 0.68 μmol/g), and harmful substances-adsorption capacity (GAC: 0.23 g/g; CAC: 14.80 mg/g; SCAC: 0.49 g/g) than HPIDF due to the changes of structure caused by fermentation. In addition, with the fermentation of HPIDF, some beneficial substances were produced, which might be potential intestinal prebiotics. The study of F-HPIDF strengthens the speculation that HPIDF may have potential bioactivities after entering the colon, which proved that okara-HPIDF may have potential functionality.

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“…While, as the pH value increasing, due to the proton depriving by base, the adsorption capacity significantly increased. A novel hemicellulose based hydrogels were designed by Ferrari and coworkers (Ferrari et al, 2014). The amidoamine was introduced into the backbone of the hemicellulose, through water based free radical graft copolymerization and cross-linking.…”

Section: Applications Of Hemicellulose Based Hydrogelsmentioning

confidence: 99%

Hemicellulose-Based Hydrogels Present Status and Application Prospects: A Brief Review

Hu¹,

Du²,

Zhang³

2018

OJF

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Hemicellulose is one of the most abundant natural resources, which extensively exist in the pant tissues as the compositions of the cell wall filling between lignin and cellulose. In this review, the hemicellulose based hydrogels was illustrated in details including the hemicellulose derivatives (such as precursor of hemicellulose based hydrogel), hydrogels fabrication methods, origin of hemicellulose, composite hydrogels, and so on. In addition, the authors as well overviewed the new methods for fabrication of hemicellulose based hydrogels and special functional hemicellulose based hydrogels.

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Design of renewable poly(amidoamine)/hemicellulose hydrogels for heavy metal adsorption

Cited by 35 publications

References 37 publications

Wood-Derived Materials for Green Electronics, Biological Devices, and Energy Applications

Wood-Derived Materials for Green Electronics, Biological Devices, and Energy Applications

Changes of High-Purity Insoluble Fiber from Soybean Dregs (Okara) after Being Fermented by Colonic Flora and Its Adsorption Capacity

Hemicellulose-Based Hydrogels Present Status and Application Prospects: A Brief Review

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