“…Block copolymer (BCP) self-assembly can generate a range of nanostructures that have many potential applications in photonics, − plasmonics, , electronics, , nanometrology, filtration membranes, , and energy devices. , Directed self-assembly (DSA) of BCPs using topographic or chemical prepatterns to render long-range order has been intensively studied because it is a promising next-generation lithography technique that can offer sub-photolithographic resolution with minimum cost. − For example, a recent DSA study using line templates successfully demonstrated finFET fabrication at the 7 nm node, in which the device performance is comparable to that of the finFETs manufactured using photolithography . DSA has also been used as a complementary lithographic method for contact hole patterning in two-dimensional (2D) templates. − Two-dimensional templates have been used to generate interesting nanostructures including spirals, rings, and line patterns with 90° bends and T-junctions. − In particular, we showed that structures with two degenerate orientations could be formed using a square template, and the degeneracy could be broken (i.e., one of the possible orientations selected) by placing openings around the edges of the templates . However, the controllability of orientation via the wall openings is limited in the sense that the orientation of neighboring cells cannot always be controlled independently.…”