The present work reports the potential of a bio-inspired system based on spectrometry, also known as Electronic Eye (EE), capable of detecting different Tequila samples. The reported system analyzes small volumes of Tequila Reposado and Blanco by calculating samples’ absorbances, using a low cost and portable instrumentation employing a CCD camera. The absorbance imaging method consisted of exciting samples with light passes through an 8MP camera connected to a Raspberry Pi Card. The camera’s image data are analyzed using MATLAB 2018b to be represented in Red, Green and Blue (RGB) components for each pixel, in order to get an approximation of the absorbance and the Surface Color Index (Isc) associated with sample concentration. Using the developed EE, it was possible to identify seven different kinds and brands of Tequila. From the obtained results, it was observed that the average absorbance of the Tequila Reposado was greater than the absorbance of the Tequila Blanco. Otherwise, with the Isc, the Tequila Blanco color index is lower concerning the Tequila Reposado’s. Finally, the EE allowed the identification of Tequila samples with reproducibility and repeatability.