Organic thin-film field-effect transistors (FETs) have been studied extensively over the last decade, and tremendous progress in device performance has been achieved.[1] OrganicFETs have worked mainly as unipolar p-type transistors, in which positive charges are accumulated in the channel by applying a negative gate voltage, V G . As a result, the state-ofthe-art integrated circuits based on organic FETs are based on unipolar p-type logic.[2] For memory applications, organic transistors with a ferroelectric gate dielectric have recently been investigated. [3][4][5] In this type of device the memory effect arises from the attenuation of the surface charge density in the semiconductor by the remanant polarization of the ferroelectric. The fingerprint of ferroelectric switching, a sharp change of the channel conduction at the coercive field of the ferroelectric, was clearly observed in solution-processed polymer ferroelectric FETs (FeFETs) with a p-type unipolar semiconductor layer. [3] It was shown that the induced surfacecharge density has a high value compared to what can be obtained with conventional Si ++ /SiO 2 transistors, and, as a result, high on/off ratios of 10 4 were achieved.From a performance point of view, however, complementary metal oxide semiconductor (CMOS) logic is crucial. The advantages compared with unipolar logic are low power dissipation, higher operating frequencies, a good noise margin, and robust operation. Therefore, the transport of electrons and holes, the so-called ambipolar charge transport, in FETs is a highly desirable property. Although the first single-channel inorganic ambipolar FETs have been demonstrated more than two decades ago, [6] their organic counterparts have only become a reality in recent years. [7][8][9][10][11][12][13] For organic FETs employing only a single active film, ambipolar charge transport was reported for heterogeneous blends consisting of polymerbased interpenetrating networks as well as narrow bandgap organic semiconductors. [12] We present a new type of organic FET consisting of an ambipolar semiconductor with a fer-
COMMUNICATIONS
2692