2008
DOI: 10.1021/je700703h
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Density and Viscosity Studies of Aqueous Solutions of Cesium Trifluoroacetate at Different Temperatures

Abstract: Densities and viscosities of aqueous solutions of cesium trifluoroacetate have been measured at T ) (298.15, 303.15, 308.15, and 313.15) K and at atmospheric pressure. Apparent molar volume (φ v ), partial molar volume (φ o v ), and the ion-ion interaction parameter (S v ) have been calculated from experimental values of densities. The calculated values for φ o v are (105.522

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Cited by 8 publications
(5 citation statements)
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“…Masses were recorded on a Dhona balance with a precision of ± 1·10 −7 kg. The densities (ρ) of aqueous solutions were measured with the help of a 15·10 −6 m 3 double arm pycnometer. , The uncertainty in the density measurements was ± 1·10 −7 kg·m −3 .…”
Section: Methodsmentioning
confidence: 99%
See 1 more Smart Citation
“…Masses were recorded on a Dhona balance with a precision of ± 1·10 −7 kg. The densities (ρ) of aqueous solutions were measured with the help of a 15·10 −6 m 3 double arm pycnometer. , The uncertainty in the density measurements was ± 1·10 −7 kg·m −3 .…”
Section: Methodsmentioning
confidence: 99%
“…The dynamic viscosity of solutions was calculated using the equation where ρ, ρ o , t , t o , and η, η o are density, flow time, and viscosity of aqueous solutions and water, respectively. Viscosity measurements were made in a transparent glass-walled water bath having a thermal stability of 0.01 K. Viscosity measurements were made as a function of concentration (0.0080 and 1.0000) mol·kg −1 of salts and temperature (298.15 and 308.15) K at atmospheric pressure. The uncertainty in the viscosity measurements was 3·10 −6 m −1 ·kg·s −1 .…”
Section: Methodsmentioning
confidence: 99%
“…The structure formation and breaking in liquids can be considered from solute solvent interactions, [2][3][4][5][6][7].…”
Section: Introductionmentioning
confidence: 99%
“…Density studies of aqueous solutions of salt are useful in understanding the nature of solute−solvent and ion−solvent interactions. Density data of aqueous solutions of salts are also required for molecular biology applications . The ion−solvent interaction is also a very important tool for the many practical problems concerning energy transport, mass transport, and fluid flow …”
Section: Introductionmentioning
confidence: 99%
“…Density data of aqueous solutions of salts are also required for molecular biology applications. 12 The ion-solvent interaction is also a very important tool for the many practical problems concerning energy transport, mass transport, and fluid flow. 13 The purpose of the present study was to evaluate structural changes in terms of ion-ion and ion-solvent interactions of sodium chloride in aqueous and aqueous maltose systems.…”
Section: Introductionmentioning
confidence: 99%