Densities and Viscosities of Binary Mixtures of exo-Tetrahydrodicyclopentadiene with N-Undecane or N-Tetradecane at T = (293.15 to 313.15) K

Zhang, Lingling; Guo, Yihang; Wei, Hui; Yang, Fengjun; Fang, Wenjun; Lin, Ruisen

doi:10.1021/je100313a

Cited by 33 publications

(16 citation statements)

References 16 publications

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“… a Standard uncertainties u are u ( T ) = 0.01 K, and expanded uncertainties U c (μ) = 0.008 mPa·s unless otherwise indicated by “±” symbol, (level of confidence = 0.95, k = 2). b Reference . c Reference . d Reference . e Reference . f Reference . g Reference . h Reference . i Reference . j Reference . l Reference . m Reference . n Reference . …”

Section: Resultsmentioning

confidence: 99%

Density, Viscosity, Speed of Sound, Bulk Modulus, Surface Tension, and Flash Point of Binary Mixtures of Butylbenzene + Linear Alkanes (n-Decane, n-Dodecane, n-Tetradecane, n-Hexadecane, or n-Heptadecane) at 0.1 MPa

et al. 2016

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This work reports physical property measurements of binary mixtures of butylbenzene with n-decane, n-dodecane, n-tetradecane, n-hexadecane, or n-heptadecane. Densities and viscosities were measured at temperatures from (293.15 to 373.15) K, and speeds of sound were measured at temperatures from (293.15 to 333.15) K, except for those of n-heptadecane, which were measured starting at 303.15 K. Densities increased with increasing mole fraction of butylbenzene. Excess molar volumes were positive and increased with increasing alkane chain length, except for those of heptadecane which were similar to those of n-hexadecane. Analysis of excess molar volumes using the Prigogine–Flory–Patterson model showed that the interaction term contributed more to excess molar volume than the free volume or P* term. As the mole fraction of butylbenzene increased, speeds of sound increased for n-decane and n-dodecane mixtures but decreased for other alkane mixtures to values below those of both pure components before increasing again. Viscosities decreased as the mole fraction of butylbenzene increased except for those of some n-decane mixtures, which were below those of butylbenzene and n-decane. Viscosity mole fraction data were fit using the three-body McAllister model. Bulk moduli and surface tension increased with increasing mole fraction of butylbenzene, and flash points fell between those of the individual components. These mixtures can be used as surrogates for petroleum-based fuels.

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Section: Resultsmentioning

confidence: 99%

Density, Viscosity, Speed of Sound, Bulk Modulus, Surface Tension, and Flash Point of Binary Mixtures of Butylbenzene + Linear Alkanes (n-Decane, n-Dodecane, n-Tetradecane, n-Hexadecane, or n-Heptadecane) at 0.1 MPa

et al. 2016

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“…It is a candidate fuel for supersonic aircraft and hypersonic missile. A large amount work have been put into investigating the thermophysical properties of JP-10 including density, viscosity, heat capacity, vapor pressure, and speed of sound, etc. − as well as its thermal and chemical stability − which is necessary for its application.…”

Section: Introductionmentioning

confidence: 99%

Measurement and Correlation of the Solubilities of Oxygen, Nitrogen, and Carbon Dioxide in JP-10

Liu

Bai

et al. 2017

J. Chem. Eng. Data

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New experimental solubility data of nitrogen, oxygen, and carbon dioxide in JP-10 (exotetrahydrodicyclopentadiene) in the temperature range from 293 to 343 K in the intervals of 10 K and in the pressure range from 0.5 to 7.5 MPa were reported. The relative expanded uncertainty of solubility measurement is estimated to be less than 4% with a level of confidence of 95%. The solubility order of the three gases in JP-10 in the studied temperature and pressure range is carbon dioxide > oxygen > nitrogen. The Henry’s constants and the thermodynamic properties of solvation were calculated from the solubility data. A modified KK equation was used to represent the experimental data with AARD less than 1.9%.

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“… a Standard uncertainties u are u ( p ) = 0.5 kPa and u ( T ) = 0.01 K. The combined standard uncertainties are u r ( ρ ) = 0.0006 and u r ( η ) = 0.01. b Reference . c Reference . d Reference . e Reference . f Reference . g Reference . h Reference . i Reference . j Reference . k Reference . l Reference . m Reference . n Reference . …”

Section: Resultsmentioning

confidence: 99%

Densities and Viscosities for the Ternary Mixture of n-Undecane (1) + Methyl Decanoate (2) + n-Butanol (3) and Corresponding Binaries from T = 293.15 to 333.15 K and at Atmospheric Pressure

Jiang

Dai

et al. 2021

J. Chem. Eng. Data

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It has been proved that the general performance of aviation fuels can be improved with the addition of biofuels. To understand the fundamental physical properties of the blends, n-undecane, methyl decanoate, and n-butanol were chosen as model compounds to construct a mixed system. Densities (ρ) and viscosities (η) of the ternary system n-undecane + methyl decanoate + n-butanol and its corresponding binary systems n-undecane + methyl decanoate, n-undecane + n-butanol, and methyl decanoate + n-butanol were measured at different temperatures T = (293.15–333.15 K) and atmospheric pressure p = 0.1 MPa. The excess molar volumes (V m E) and the viscosity deviations (Δη) of the binary systems and the ternary system were correlated to the Redlich–Kister equation and four semi-empirical equations, respectively. The V m E values of the ternary system and binary systems are all positive over the entire concentration range at each experimental temperature, while their Δη values are all negative. The experimental results can provide reliable data for the compatibility of biofuels and fossil fuels.

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Densities and Viscosities of Binary Mixtures of exo-Tetrahydrodicyclopentadiene with N-Undecane or N-Tetradecane at T = (293.15 to 313.15) K

Cited by 33 publications

References 16 publications

Density, Viscosity, Speed of Sound, Bulk Modulus, Surface Tension, and Flash Point of Binary Mixtures of Butylbenzene + Linear Alkanes (n-Decane, n-Dodecane, n-Tetradecane, n-Hexadecane, or n-Heptadecane) at 0.1 MPa

Density, Viscosity, Speed of Sound, Bulk Modulus, Surface Tension, and Flash Point of Binary Mixtures of Butylbenzene + Linear Alkanes (n-Decane, n-Dodecane, n-Tetradecane, n-Hexadecane, or n-Heptadecane) at 0.1 MPa

Measurement and Correlation of the Solubilities of Oxygen, Nitrogen, and Carbon Dioxide in JP-10

Densities and Viscosities for the Ternary Mixture of n-Undecane (1) + Methyl Decanoate (2) + n-Butanol (3) and Corresponding Binaries from T = 293.15 to 333.15 K and at Atmospheric Pressure

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