“…However, when investigating bubble–solid interactions, the solid surface is often considered to be chemically homogeneous. Typically, surface heterogeneity originates from crystal defects on a nanoscale, which are caused by missing or misplaced atoms in the crystal lattice, or association between various components. , On the macroscale, defects created by incomplete liberation after crushing and grinding, the adsorption of flotation reagents, the non-uniform dissociation and oxidation of surface functional groups, , or slime on the mineral surface − always induce heterogeneous. In particular, for coal, which is an organic sedimentary rock composed of inorganic and organic substances, defect-free coal surfaces are difficult to be achieved.…”