2019
DOI: 10.1134/s0020168519010102
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Delocalized-Atom Model and Properties of Sulfophosphate Glasses

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Cited by 3 publications
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“…This may be due to a gradual depolymerization of the glass network and the formation of more NBOs and short chain composed by sulfate, borate and phosphate structural units. Indeed, it was suggested that the sulfophosphate glass network is made up of relatively short -P-O-P-chains where SO 4 tetrahedra bind to such chain as terminal groups [36]. One possibility to explain the depolymerization mechanism is that SO 2− 4 ions interact with PO 4 units by forming P-O-S bonds to disconnect the phosphate network.…”
Section: Optical Band Gap and Urbach Energymentioning
confidence: 99%
“…This may be due to a gradual depolymerization of the glass network and the formation of more NBOs and short chain composed by sulfate, borate and phosphate structural units. Indeed, it was suggested that the sulfophosphate glass network is made up of relatively short -P-O-P-chains where SO 4 tetrahedra bind to such chain as terminal groups [36]. One possibility to explain the depolymerization mechanism is that SO 2− 4 ions interact with PO 4 units by forming P-O-S bonds to disconnect the phosphate network.…”
Section: Optical Band Gap and Urbach Energymentioning
confidence: 99%