We have previously shown from static planar conductance measurements that a strong inversion layer does exist in c‐Si at the (n) a‐Si:H/ (p) c‐Si interface. This allowed us to determine the conduction band offset with a good precision (ΔEC = 0.15 +/– 0.04 eV). The same technique is now applied to study (p) a‐Si:H/ (n) c‐Si interfaces. We demonstrate that a strong inversion layer (of holes) also exists at the c‐Si surface of this hetero‐interface. Analysis of our planar conductance data with the help of numerical simulations allows us to set a lower limit to the valence band offset, ΔEV = EV,a‐Si:H − EV, c‐Si: ΔEV > 0.28 eV. (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)