This study assessed the effect of acetic NaF solutions on stainless steel orthodontic brackets. Acetic acid was added to a 0.1% NaF solution to make two solutions, one with pH 3.5 and the other with pH 6. For the two different stainless steel brackets(Tomy, Dentaurum)used in this study, they had a similar elemental composition -except with Mo(molybdenum) in the Tomy bracket. The brackets were then immersed in the prepared test solutions for three days and their responses evaluated. In terms of hydrofluoric acid(HF)concentration, the 0.1%/pH 3.5 solution showed a high HF concentration at 227 ppm, while that of 0.1%/pH 6 solution was very low at 7 ppm. In terms of color change and element release, only the Dentaurum brackets in 0.1%/pH 3.5 solution showed an appreciable color change(ΔE * =4.0)and released a great amount of elements(Fe, Cr, Ni, Mn)after three days. Otherwise, regardless of pH value and product, only minor color change (ΔE * <1.0)and negligible element release occurred. In terms of surface modification, no visible changes in surface morphology were observed in any product after immersion in test solutions.