We present low-resolution (R ∼ 90) and medium-resolution (R ∼ 2500) spectropolarimetry of Nova V475 Sct with the HBS instrument, mounted on the 0.91-m telescope at the Okayama Astrophysical Observatory, and with FOCAS, mounted on the 8.2-m Subaru telescope. We estimated the interstellar polarization toward the nova from the steady continuum polarization components and Hα line emission components. After subtracting the interstellar polarization component from the observations, we found that the Hα emission seen on 2003 October 7 was clearly polarized. In the polarized flux spectrum, the Hα emission had a distinct red wing extending to ∼ +4900 km s −1 and a shoulder around +3500 km s −1 , showing a constant position angle of linear polarization θ * ≃ 155 • ±15 • . This suggests that the nova had an asymmetric outflow with a velocity of v wind ≃ 3500 km s −1 or more, which is six times higher than the expansion velocity of the ionized shell at the same epoch. Such a high-velocity component has not previously been reported for a nova in the 'moderately fast' speed class. Our observations suggest the occurrence of violent mass-loss activity in the nova binary system even during the common-envelope phase. The position angle of the polarization in the Hα wing is in good agreement with that of the continuum polarization found on 2003 September 26 (p * ≃ 0.4-0.6 %), which disappeared within the following 2 d. The uniformity of the PA between the continuum polarization and the wing polarization on October 7 suggests that the axis of the circumstellar asymmetry remained nearly constant during the period of our observations.