Abstract:ABSTRACT:Radical polymerization of isopropenyl acrylate (IPA) and methacrylate (IPMA) was investigated at 60oC in benzene. The residual double bond in the polymers was determined to be mainly isopropenyl groups by spectroscopy and titrimetry. The decrease in the residual double bonds of polymers with decreasing initial monomer concentration can be explained in terms of an intramolecular chain monocyclization-bicyclization mechanism, in which the monocyclization took place between a growing polymer radical and … Show more
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