1958
DOI: 10.1021/ja01550a084
|View full text |Cite
|
Sign up to set email alerts
|

Cyclopentadienyltitanium Trichloride

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1
1

Citation Types

0
20
0

Year Published

1962
1962
2008
2008

Publication Types

Select...
6

Relationship

0
6

Authors

Journals

citations
Cited by 65 publications
(20 citation statements)
references
References 0 publications
0
20
0
Order By: Relevance
“…[38] Deuterated solvents were firstly degassed by several freeze-thaw cycles, held at room temperature over fresh activated 4 Å molecular sieves (10 % w/v) for several days, and then stored at room temperature over freshly activated 4 Å molecular sieves (10 % w/v). Compounds TiCpCl 3 [39,40] and Ti(η 5 -C 5 H 4 SiMe 2 Cl)Cl 3 [41] were prepared by a known procedure. Aniline, p-toluidine, cyclohexylamine, 2,6-dimethylaniline, 3,5-di-tert-butyl-2-hydroxybenzaldehyde, salicylaldehyde, paraformaldehyde, 2,4-ditert-butylphenol, LiBH 4 , NaBH 4 and AlLiH 4 , LiMe (1.6  solution in Et 2 O) or MgClMe (3  solution in thf), MgClEt (2  solution in Et 2 O) and LiPh [2  solution in cyclohexane/ethyl ether mixture (Aldrich)] were used as received.…”
Section: Methodsmentioning
confidence: 99%
“…[38] Deuterated solvents were firstly degassed by several freeze-thaw cycles, held at room temperature over fresh activated 4 Å molecular sieves (10 % w/v) for several days, and then stored at room temperature over freshly activated 4 Å molecular sieves (10 % w/v). Compounds TiCpCl 3 [39,40] and Ti(η 5 -C 5 H 4 SiMe 2 Cl)Cl 3 [41] were prepared by a known procedure. Aniline, p-toluidine, cyclohexylamine, 2,6-dimethylaniline, 3,5-di-tert-butyl-2-hydroxybenzaldehyde, salicylaldehyde, paraformaldehyde, 2,4-ditert-butylphenol, LiBH 4 , NaBH 4 and AlLiH 4 , LiMe (1.6  solution in Et 2 O) or MgClMe (3  solution in thf), MgClEt (2  solution in Et 2 O) and LiPh [2  solution in cyclohexane/ethyl ether mixture (Aldrich)] were used as received.…”
Section: Methodsmentioning
confidence: 99%
“…NEt 3 (Aldrich) was distilled before use and stored over 4 Å molecular sieves. [Ti(η 5 -C 5 H 5 )Cl 3 ], [28] [Ti(η 5 -C 5 Me 5 )Cl 3 ], [29] [Ti(η 5 -C 5 H 4 SiMe 3 )Cl 3 ], [30] [Zr(η 5 -C 5 H 5 )Cl 3 ]·DME [31] and [Zr(η 5 -C 5 Me 5 )Cl 3 ] [32] were prepared by known procedures. Polymerization-grade ethylene was used as received.…”
Section: Methodsmentioning
confidence: 99%
“…[la]. To a soln./suspension of trichlorojcyclopentadieny1)titanium (2) [28] (1 1 .O g, 50 mmol, freshly sublimed) in 400 ml of dry Et,O 1,21S,6-di-O-isopropy/idene-~-D-glucofuranose (3, 26.0 g, 100 mmol; crystallised from cyclohexane) was added (Ar, exclusion of moisture). After stirring for 2 min at r.t., a soln.…”
Section: Experimental Partmentioning
confidence: 99%
“…To a soln./suspension of 2 [28] (1 I .0 g, 50.1 mmol; freshly sublimed) in 400 ml ofdry Et20, i-PrOH (6.0 g, 100 mmol; dried over4-A molecular sieves) and, after 5 min, Et,N (15.2 ml, 110 mmol) in 125 ml of Et20 were added dropwise within 1 h (Ar). After stirring over night at r.t., Et,N .HCI (13.5 g after drying) was removed by filtralion under Ar and washed with Et20 (3 x 50 ml).…”
Section: Chloro(cyclopentadnyl)bis(i2:5~-di-0-isopropylidene-a-o-glmentioning
confidence: 99%