The FeCrAlRE (where RE is reactive element) alloy Kanthal AF was exposed isothermally at 600 and
800°C
for 72 h in dry
normalO2
and in
normalO2
with 10 vol %
normalH2O
. The mass gains were 3–5 times higher at the higher temperature. The presence of water vapor increased the oxidation rate at
800°C
, while no significant effect was observed at
600°C
. A thin two-layered oxide formed at
600°C
: an outer
(Fe,Cr)2normalO3
corundum-type oxide, containing some Al, and an inner, probably amorphous, Al-rich oxide. At
800°C
a two-layered oxide formed in both environments. The inner layer consisted of inward grown
α-Al2normalO3
. In dry
normalO2
the originally formed outward grown
γ-Al2normalO3
had transformed to
α-Al2normalO3
after 72 h. Water vapor stabilized the outward grown
γ-Al2normalO3
and hence no transformation occurred after 72 h in humid environment. RE-rich oxide particles with varying composition (Y, Zr, and Ti) were distributed in the base oxide at both temperatures and in both environments. The RE-rich particles were separated from the alloy substrate by a layer of Al-rich oxide. At
800°C
the Y-rich RE particles were surrounded by thick oxide patches in both dry and humid
normalO2
.