“…This symmetrical pentanuclear unit interacts with four neighboring units by forming an out-of-plane dimeric moiety in the [Mn III (saltmen)] + moieties as shown in Section 4, consequently constructing a 2D network having a dodecanuclear [ Mn III (O Ph ) 2 Mn III NC Fe III CN ] 4 cyclic repeat unit. Therefore, the Mn(III) ion has a distorted square bipyramidal geometry, in which the two apical sites are occupied by the nitrogen atom from [Fe III (CN) 6 [116]. The dc magnetic measurements displayed similar magnetic properties (J = 2.34(7) cm −1 , g = 2.04(2), zJ = 0.036(4) cm −1 ) exhibiting a long-range order at T c = 4.8 K.…”