Cyanide‐Bridged Complexes of Transition Metals: A Molecular Magnetism Perspective

Crystal structure of tris(cyano-(hydrogen tris(3,5-dimethylpyrazolyl)borate))-iron(III) 4-methoxypyridinium monohydrate, C24H32BN10O2Fe

“…As one of the most well-known bridging groups for magnetic complexes, the cyanide ligand exhibits unique advantages for the assembly of new molecular magnetic materials, not only because the resulting structures can be easily predicted but also because mediation of magnetic coupling between (heterospin) metal centres can be expected. Up to date, a large number of cyanide-bridged complexes with interestingly magnetic properties have been obtained [8][9][10][11][12][13] …”

Evolution of thermodynamic properties and inelastic neutron scattering intensities for spin-12antiferromagnetic quantum rings

“…Nanomagnetism continues to be a highly-active research area in condensed matter physics due to the potential for spintronic devices through the coupling of electronic and magnetic degrees of freedom [1][2][3][4][5][6][7][8][9][10][11][12][13] . The interactions in nanomagnetic systems range from long-range interactions that produce spin-waves and skyrmionic orders to short-range magnetic cluster that exhibit discrete excitations.…”

“…Magnetic clusters are typically considered to be a grouping of magnetic ions, in various geometric configurations, that are isolated from long-range magnetic interactions through non-magnetic ligands [1][2][3][4][5][6][7][8][9][10][11][12][13] . These include Mn 12 and Mn 84 or Fe 8 5-7 .…”

The First Homoleptic Complex of Seven-Coordinated Osmium: Synthesis and Crystallographical Evidence of Pentagonal Bipyramidal Polyhedron of Heptacyanoosmate(IV)

“…The research in the area of cyanides has been the subject of several reviews over the years [4,5,[23][24][25][26]. However, the scarce amount of information on homoleptic osmium cyanide complexes is astounding [23,[27][28][29][30][31][32].…”