“…Due to tremendous effort of many research organizations and industries, state-of-art TSV forming and copper via filling can be successfully developed. As TSV vertical interconnection methods, Cu pillar/Sn-Ag bump structure is being widely investigated for 3D TSV chip stacking [2][3][4][5][6][7][8]. Recently, 40 lm pitch TSV-chip stacking is being applied in real products in IBM, Xillinx, Samsung, etc., however, there are two major problems in Cu pillar/ Sn-Ag bonding.…”