Crystallographic report: Chain-like crystal structure of [Ni(en)2Ag(CN)2] [Ag(CN)2]

Silver(I) salts demonstrate a strong preference for forming linear complexes when reacted with 4-(phenylethynyl)pyridine (pep). The packing of these complexes was found to be strongly influenced by the counteranions, namely PF 6 -, BF 4 -, NO 2 -, NO 3 -, MeCO 2 -, CF 3 CO 2 -, MeSO 3 -, Tosand SCN -. This study evaluates a family of twelve solid-state structures that exhibit varying metal-to-ligand ratios, [Ag(pep) 2 ][PF 6 ]· MeCN, [Ag(pep) 2 ][PF 6 ], [Ag(pep) 2 ][BF 4 ], [Ag(pep) 2 ][Ag(NO 2 ) 2 ], [Ag(pep) 2 ][NO 3 ]·2H 2 O, [Ag(pep) 2 ][Ag(NO 3 ) 2 ], [Ag(pep) 2 (MeCO 2 )]· [a]

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Exploring Structure–Property Relationships of Silver 4‐(Phenylethynyl)pyridine Complexes

Knichal

Gee

Cameron

et al. 2017

Eur J Inorg Chem

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Synthesis and Crystal Structure of a Cyano-Bridged Bimetallic Nickel(II)–Silver(I) Complex, [Ni(dmen)2{Ag(CN)2}2] · 0.5H2O

et al. 2007

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An Interpenetrating Coordination Polymer Containing Weak Hydrogen Bonds and Argentophilic Interactions

2006

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Crystallographic report: Chain-like crystal structure of [Ni(en)2Ag(CN)2] [Ag(CN)2]

Cited by 7 publications

References 8 publications

Exploring Structure–Property Relationships of Silver 4‐(Phenylethynyl)pyridine Complexes

Exploring Structure–Property Relationships of Silver 4‐(Phenylethynyl)pyridine Complexes

Synthesis and Crystal Structure of a Cyano-Bridged Bimetallic Nickel(II)–Silver(I) Complex, [Ni(dmen)2{Ag(CN)2}2] · 0.5H2O

An Interpenetrating Coordination Polymer Containing Weak Hydrogen Bonds and Argentophilic Interactions

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