Crystalline architectures at the air-liquid interface: From nucleation to engineering

Rapaport, Hanna; Kuzmenko, Ivan; Kjær, Kristian; Als‐Nielsen, J.; Weissbuch, Isabelle; Lahav, Meir; Leiserowitz, Leslie

doi:10.1080/08940889908260985

Cited by 5 publications

(1 citation statement)

References 23 publications

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“…3.1 | "Bottom-up" interfacial method "Bottom-up" interfacial method refers to the synthesis of ultra-thin 2D polymers on solid surface, liquid surface, or liquid-liquid interface. This method can effectively control the polymerization only in 2D direction, so many independent 2D polymers, such as graphene, [65][66][67] graphitic alkyne, 68 COFs 69-71 and some other kinds of organic 2D polymers, [72][73][74][75][76][77][78][79][80] were prepared by this method.…”

Section: Covalent Organic 2d Polymersmentioning

confidence: 99%

Synthesis methods of organic two‐dimensional materials

Zhang

Wang

2020

Journal of Polymer Science

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Among various two‐dimensional (2D) materials, organic 2D polymers have attracted much attention, owing to their specific properties, such as lightweight, good flexibility, adjustable structure, and high adaptability. In recent years, more and more scientists have devoted to the research on their structural design, synthesis, characterization, and potential properties. However, in contrast to traditional one‐dimensional (1D) and three‐dimensional (3D) network macromolecules, the synthesis of 2D structures presents a challenge to polymer chemists, because polymerization usually takes place in a spatially random manner in solution‐phase synthesis. In this review, we will focus on the synthesis methods of organic 2D materials, which have played a pivotal role since the beginning of the development of this field. We will highlight the representative examples according to the different types of polymers, including supramolecular organic 2D layers and covalent organic 2D polymers, and identify possible future research directions.

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