2000
DOI: 10.1017/s0885715600011131
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Crystal structure of the monoclinic perovskite Sr3.94Ca1.31Bi2.70O12

Abstract: The crystal structure of the low-temperature oxidized form of Sr^^CaigsBi^O^j has been determined using a combination of neutron, synchrotron, and laboratory X-ray powder diffraction data. The structure is pseudo-orthorhombic; systematic absences and successful refinement indicated the true structure to be monoclinic, with space group P2,/n. Structural refinement using only neutron powder data yielded the lattice parameters a = S.38 898 (29) A, £=5.99 334(21) A, c=5.89 586(20) A, /3= 89.997(8)°, and V=296.43(3… Show more

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Cited by 4 publications
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“…The structure of the LT- form (black) is monoclinic (pseudo-orthorhombic (Fig. 38), with space group P 2 1 / n [120]. Structural refinements using neutron data gives the lattice parameters of (Bi 34 Sr 49.5 Ca 16.5 O 151 ) as: a = 8.38931(16) Å, b = 5.99445(11) Å, c = 5.89572(11) Å, β = 89.961(3)°, and V = 296.49(1) Å 3 .…”
Section: Phase Equilibria and Crystallographic Studies Of High-temmentioning
confidence: 99%
“…The structure of the LT- form (black) is monoclinic (pseudo-orthorhombic (Fig. 38), with space group P 2 1 / n [120]. Structural refinements using neutron data gives the lattice parameters of (Bi 34 Sr 49.5 Ca 16.5 O 151 ) as: a = 8.38931(16) Å, b = 5.99445(11) Å, c = 5.89572(11) Å, β = 89.961(3)°, and V = 296.49(1) Å 3 .…”
Section: Phase Equilibria and Crystallographic Studies Of High-temmentioning
confidence: 99%