Crystal structure of (E)-3-(3-(5-methyl-1-4-tolyl-1H-1,2,3-triazol-4-yl)-1-phenyl-1H-pyrazol-4-yl)-1-(5-methyl-1-phenyl-1H-1,2,3-triazol-4-yl)prop-2-en-1-one, C₃₁H₂₆N₈O

Abstract

C31H26N8O, triclinic, P1̄ (no. 2), a = 6.6046(3) Å, b = 15.1056(8) Å, c = 15.2115(8) Å, α = 61.996(2)°, β = 80.390(3)°, γ = 87.579(2)°, V = 1319.97(12) Å3, Z = 2, Rint = 0.108, wR(F2) = 0.143, T = 296(2) K.

The crystal structure of 5-(2-(4-fluorophenyl)hydrazono)-4-methyl-2-((3-(5-methyl-1-(4-methylphenyl)-1H-1,2,3-triazol-4-yl)-1-phenyl-1H-pyrazol-4-yl)methylene) hydrazono)-2,5-dihydrothiazole dimethylformamide monosolvate, C30H25FN10S⋅C3H7NO

“…The synthesis of pyrazoles can be achieved by performing a condensation of hydrazines and unsaturated carbonyl containing compounds [11], whereas thiazoles can be efficiently synthesized through various reactions such Gabriel, Hantzsch and Cook-Heilborn's syntheses [12]. Recently, the X-ray crystal structures for related heterocycles have been reported [13][14][15][16]. C/E = 7.91 (14)°.…”

“…Recently, the X-ray crystal structures for related heterocycles have been reported [13][14][15][16]. C/E = 7.91 (14)°. The plane of the methylphenyl group F deviates from the plane of the rest of the molecule with a twist angle E/F = 43.78(8)°.…”