Crystal structure of catena-poly[(5,5,7,12,12,14-hexamethyl -1,4,8,11-tetraazacyclotetradecane- κ ⁴ N,N′,Nʺ,N‴)nickel(II)-(μ₂-perchlorato-κ ² O:O′)] 3,5-dicarboxybenzoate – methanol (1/2), C₂₇H₄₉ClN₄NiO₁₂

Abstract

C27H49ClN4NiO12, triclinic, P 1 ‾ $\overline{1}$ (no. 2), a = 11.180(2) Å, b = 12.320(3) Å, c = 12.754(3) Å, α = 98.263(2)°, β = 97.524(2)°, γ = 99.470(2)°, V = 1693.1(6) Å3, Z = 2, R gt(F) = 0.0423, wR ref(F 2) = 0.1238, T = 296(2) K.

Flexible Co(II)-and Ni(II)-Based Cationic 2D Metal–Organic Frameworks Based on a Charge-Neutral (O,O)-Donor Bridge

“…Examples of Co(II) and Ni(II) perchlorates with anionic bridges are much rarer [67,68]. A few works also report the coordination of perchlorate with Co(II) or Ni(II) within the relevant polymeric networks [69,70].…”

“…Examples of Co(II) and Ni(II) perchlorates with anionic bridges are much rarer [67,68]. A few works also report the coordination of perchlorate with Co(II) or Ni(II) within the relevant polymeric networks [69,70]. According to the PLATON [71] estimation, the layered coordination network in 1 and 2 possesses 20% total void volume, if erasing dioxane from the structure.…”