Crystal structure of dinitratobis(4-methyl-5-formyl-imidazolfuranoylhydrazone) gadolinium(III) mononitrate, [Gd{(OC(C4H3O)NHNCH(CH3)C3H2N2)}2(NO3)2][NO3]

Haba, P. M.; Diouf, Ousmane; Gaye, Mohamed; Sall, Abdou Salam; Barry, Aliou Hamady; Weller, Ruth; Chahrazed, B.

doi:10.1524/ncrs.2005.220.14.421

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2020

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“…These kinds of Schiff bases were used for preparing complexes with transition-metal or lanthanide ions. The ligand acts in a bidentate or tridentate fashion, as reported in the literature [ABUKIU (Singh et al, 2017), DAZMEX (Haba et al, 2005), FIGMEO (Maurya et al, 2005), and VIVGOY (Alagesan et al, 2014)]. One organometallic palladium complex was found containing a metalcarbon bond in a six-membered ring (TAPXEQ; Qian et al, 2017).…”

Section: Supramolecular Featuresmentioning

confidence: 69%

Crystal structure ofN′-[4-(dimethylamino)benzylidene]furan-2-carbohydrazide monohydrate

et al. 2020

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The condensation of 2-furoic hydrazide and 4-dimethyl aminobenzaldehyde in ethanol yielded a yellow solid formulated as the title compound, C14H15N3O2·H2O. The crystal packing is stabilized by intermolecular O(water)—H...O,N(carbohydrazide) and N—H...O(water) hydrogen bonds, which form a two-dimensional network along the bc plane. Additional C—H...O interactions link the molecules into a three-dimensional network. The dihedral angle between the mean planes of the benzene and the furan ring is 34.47 (6)°. The carbohydrazide moiety, i.e., the C=N—N—C=O fragment and the benzene ring are almost coplanar, with an angle of 6.75 (9)° between their mean planes.

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Section: Supramolecular Featuresmentioning

confidence: 69%