2000
DOI: 10.1515/ncrs-2000-0246
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Crystal structure of chlorodiethyl(2-dimethylaminoethanethiolato) tin(IV), (C2H6NCH2CH2S)SnCl(C2H5)2

Abstract: Translation of the Bible or any other text unavoidably involves a determination about its meaning. There have been different views of meaning from ancient times up to the present, and a particularly Enlightenment and Modernist view is that the meaning of a text amounts to whatever the original author of the text intended it to be. This article analyzes the authorial-intent view of meaning in comparison with other models of literary and legal interpretation. Texts are anchors to interpretation but are subject t… Show more

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“…The equatorial coordination distances, d{Sn-S) = 2.415(2) A, d(Sn-C) = 2.118(6) A and 2.119(6) A, agree well with the sum of the corresponding covalent or atomic radii, while the apical distances ¿(Sn-CI) = 2.593(2) A and d(Sn-N) = 2.309(5) A are considerably longer. All other structural data are as expected and resemble those reported for chlorodiethyl(2-dimethylaminoethanethiolato)tin(TV) [1], Small differences are observed in the Sn-CI and Sn-N bond distances, that are 2.544(2) A and 2.388(7) A in the cited compound, whereas the Sn-S distances have the same value. A very long Sn-N distance of 2.647(2) A was found in bis(triphenyl)chlorodimethyl(2-aminoethanethiolato)tin(IV) [2], where the tin atom is four-coordinated, and a value of 2.43( 1) A was reported for the ethyl L-cysteinato derivative [3].…”
Section: Discussionsupporting
confidence: 86%
“…The equatorial coordination distances, d{Sn-S) = 2.415(2) A, d(Sn-C) = 2.118(6) A and 2.119(6) A, agree well with the sum of the corresponding covalent or atomic radii, while the apical distances ¿(Sn-CI) = 2.593(2) A and d(Sn-N) = 2.309(5) A are considerably longer. All other structural data are as expected and resemble those reported for chlorodiethyl(2-dimethylaminoethanethiolato)tin(TV) [1], Small differences are observed in the Sn-CI and Sn-N bond distances, that are 2.544(2) A and 2.388(7) A in the cited compound, whereas the Sn-S distances have the same value. A very long Sn-N distance of 2.647(2) A was found in bis(triphenyl)chlorodimethyl(2-aminoethanethiolato)tin(IV) [2], where the tin atom is four-coordinated, and a value of 2.43( 1) A was reported for the ethyl L-cysteinato derivative [3].…”
Section: Discussionsupporting
confidence: 86%