Crystal structure and characterization of a novel luminescent 1D coordination polymer: [Ca 9 (μ–H 2 O) 9 (picolinate) 18 ]·4H 2 O

Nair, Remya M.; Sudarsanakumar, M.R.; Suma, S.; Kurup, M.R. Prathapachandra; Antharjanam, P. K. Sudhadevi

doi:10.1016/j.inoche.2015.11.010

Cited by 4 publications

(4 citation statements)

References 16 publications

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“…[2] An interesting example is Ca cation which adopts coordination numbers ranging from six to nine. [23] Among them, eight-coordination is the most abundant. [23,24] Nonsteroidal anti-inflammatory drugs (NSAIDs) are among the most frequently prescribed pharmaceuticals to reduce pain and inflammation.…”

Section: Introductionmentioning

confidence: 99%

“…[23] Among them, eight-coordination is the most abundant. [23,24] Nonsteroidal anti-inflammatory drugs (NSAIDs) are among the most frequently prescribed pharmaceuticals to reduce pain and inflammation. [25] Their anti-inflammatory action relies on inhibiting the cyclooxygenase (COX) enzymes which are mediators of the inflammatory process.…”

Section: Introductionmentioning

confidence: 99%

“…Furthermore, their high coordination numbers increase coordination arrangements and prompt unusual supramolecular topologies [2] . An interesting example is Ca cation which adopts coordination numbers ranging from six to nine [23] . Among them, eight‐coordination is the most abundant [23,24] …”

Section: Introductionmentioning

confidence: 99%

“…An interesting example is Ca cation which adopts coordination numbers ranging from six to nine [23] . Among them, eight‐coordination is the most abundant [23,24] …”

Section: Introductionmentioning

confidence: 99%

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1D and 2D Coordination Polymers of Calcium with Nonsteroidal Anti‐Inflammatory Drugs: Synthesis, Crystal Structures, Hirshfeld Surfaces, Antimicrobial and Antioxidant Activities

Gacki,

Kafarska,

Korona‐Głowniak

et al. 2024

ChemPlusChem

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Four alkaline earth metal complexes of ketoprofen (Hket) and indomethacin (Hind) were synthesized and characterized: [Ca(ket)2(H2O)2]n (1), [Mg(ket)2(H2O)2] (2), [Ca(ind)2(EtOH)2]n (3), and [Mg(ind)2(EtOH)2] (4). All compounds were studied by elemental analysis (EA), flame atomic absorption spectrometry (FAAS), Fourier transform infrared spectroscopy (FTIR), and thermogravimetric analysis (TGA). Crystal structures of 1 and 3 were determined by single crystal X‐ray diffraction technique T=100 K. The structure of 1 is dominated by a one‐dimensional coordination polymer, while 3 is formed by a two‐dimensional layer stabilized by the calcium zig‐zag chains and π···π stacking interactions. Crystal packing arrangements were characterized by fingerprint plots (FPs) that were derived from the Hirshfeld surfaces (HSs). The antioxidant and antimicrobial activities of complexes were evaluated against Gram‐positive and Gram‐negative bacteria as well as yeasts.

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

“…An interesting example is Ca cation which adopts coordination numbers ranging from six to nine [23] . Among them, eight‐coordination is the most abundant [23,24] …”

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

1D and 2D Coordination Polymers of Calcium with Nonsteroidal Anti‐Inflammatory Drugs: Synthesis, Crystal Structures, Hirshfeld Surfaces, Antimicrobial and Antioxidant Activities

Gacki,

Kafarska,

Korona‐Głowniak

et al. 2024

ChemPlusChem

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Poly[tetraaquatriglutaratodicerium(III) decahydrate], a novel luminescent metal-organic framework possessing hydrophilic hexagonal channels

Nair¹,

Sudarsanakumar²,

Suma³

et al. 2016

J Chem Sci

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A novel 2D metal-organic framework poly[tetraaquatriglutaratodicerium(III) decahydrate] with an open framework structure has been successfully grown by single gel diffusion technique. Sodium metasilicate was used for gel preparation. The structure was determined by single crystal X-ray diffraction. The compound crystallizes in orthorhombic space group Pnma and possesses a structure consisting of [CeO 10 ] polyhedra and H 2 O molecules with hydrophilic hexagonal channels. The crystals were further characterized by elemental analysis, FT-IR and UV-Visible spectroscopy, powder X-ray diffraction and thermogravimetry. The luminescent property and magnetic susceptibility of the complex were also investigated.

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Facile microwave synthesis, structural diversity and herbicidal activity of six novel alkaline-earth metal complexes (AECs) based on skeletal isomerization chlorophenoxyacetic acids

et al. 2018

New J. Chem.

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Crystal structure and characterization of a novel luminescent 1D coordination polymer: [Ca 9 (μ–H 2 O) 9 (picolinate) 18 ]·4H 2 O

Cited by 4 publications

References 16 publications

1D and 2D Coordination Polymers of Calcium with Nonsteroidal Anti‐Inflammatory Drugs: Synthesis, Crystal Structures, Hirshfeld Surfaces, Antimicrobial and Antioxidant Activities

1D and 2D Coordination Polymers of Calcium with Nonsteroidal Anti‐Inflammatory Drugs: Synthesis, Crystal Structures, Hirshfeld Surfaces, Antimicrobial and Antioxidant Activities

Poly[tetraaquatriglutaratodicerium(III) decahydrate], a novel luminescent metal-organic framework possessing hydrophilic hexagonal channels

Facile microwave synthesis, structural diversity and herbicidal activity of six novel alkaline-earth metal complexes (AECs) based on skeletal isomerization chlorophenoxyacetic acids

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