1966
DOI: 10.1039/tf9666201265
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Cryoscopic determination of osmotic coefficients for ammonium chloride and bromide

Abstract: The determination by cryoscopy of precise values of the osmotic coefficients of ammonium chloride and bromide in water at 0°C shows that earlier reports of abnormal behaviour in dilute solution should be discounted. The osmotic coefficients of the ammonium salts are very similar to those of the corresponding potassium salts. Specific interaction coefficients are reported.

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Cited by 14 publications
(17 citation statements)
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“…7 Craft and Van Hook, 8 Brown and Prue, 9 and Garnsey and Prue. 10 The predicted values were determined from eq 14 where eq 2 with the suggested Huckel parameters of methods I, II, and III (see text) were used for the osmotic coefficients. Symbols in graph A (all data from ref 7): It was also possible to test the new Huckel equations for 0 °C using the electrochemical data.…”
Section: ■ Results and Discussionmentioning
confidence: 99%
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“…7 Craft and Van Hook, 8 Brown and Prue, 9 and Garnsey and Prue. 10 The predicted values were determined from eq 14 where eq 2 with the suggested Huckel parameters of methods I, II, and III (see text) were used for the osmotic coefficients. Symbols in graph A (all data from ref 7): It was also possible to test the new Huckel equations for 0 °C using the electrochemical data.…”
Section: ■ Results and Discussionmentioning
confidence: 99%
“…The sets used in the parameter estimation and the sets of Craft and van Hook (NaCl), Brown and Prue (KCl), and Garnsey and Prue (KCl) were first used to test the resulting values. The tests were performed here as in ref .…”
Section: Resultsmentioning
confidence: 99%
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