1970
DOI: 10.1002/bbpc.19700740116
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Thermodynamic Properties of Concentrated Solutions of Strong Electrolytes I. Activity Coefficients of Water From Freezing‐Point Depressions for Alkali Chlorides

Abstract: A systematic study of thermodynamic properties of concentrated solutions of strong electrolytes is undertaken. Accurate freezing‐point depressions for all the alkali chlorides up to very high concentrations (> 3m) are measured and the corresponding rational activity coefficients of the water determined. “Best” values are recalculated for the parameters of the Debye‐Hückel theory (short‐range interactions being accounted for according to the “effective dielectric constant” model and the effects of “higher te… Show more

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Cited by 20 publications
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