Cost-effective electrosynthesis of a series of edaravones through an electrochemical-assisted domino heteroannulation and paired electrochemical process

Khodaei, Mohammad Mehdi; Alizadeh, Abdolhamid; Kanjouri, Tayyebeh

doi:10.1007/s13738-015-0702-0

Cited by 2 publications

(2 citation statements)

References 38 publications

(31 reference statements)

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“…Next, following the oxidation, an intramolecular Michael‐type reaction happens in a domino fashion to provide 208a . Significantly, this compound is formed via an oxidative/intermolecular Michael‐type addition/oxidative/intramolecular Michael‐type addition (ECEC) …”

Section: Oxidationmentioning

confidence: 99%

“…Significantly, this compound is formed via an oxidative/intermolecular Michael-type addition/oxidative/intramolecular Michael-type addition (ECEC). [77] A green electrochemical methodology for the synthesis of pyrazoles 209 was reported by Radfar and co-workers in 2016. [78] Electrochemical oxidation of catechol and various 3functionalized catechol derivatives 151 was accomplished using 3-methyl-1-phenyl-1H-pyrazol-5(4H)-one 72 as the nucleophile at different pH values in aqueous solution.…”

Section: Oxidationmentioning

confidence: 99%

See 1 more Smart Citation

Electrochemically Induced Michael Addition Reaction: An Overview

Fotouhi

Heravi

Zadsirjan

et al. 2018

The Chemical Record

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Due to its high potential for the formation of carbon‐carbon bonds, Michael addition reaction is one of the closest reactions to the heart of synthetic organic chemists. Electrochemistry presents a very stimulating and divergent resource for selective oxidation and reduction in organic chemistry, generating activated species, for example radical anions or radical cations. In this review, we try to underscore usefulness of electrogenerated Michael addition reaction with the hope of encouraging synthetic organic chemists to contemplate it, as an efficient and green strategy when it is required in their designed multi‐step reaction pathways.

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Section: Oxidationmentioning

confidence: 99%

Section: Oxidationmentioning

confidence: 99%

Electrochemically Induced Michael Addition Reaction: An Overview

Fotouhi

Heravi

Zadsirjan

et al. 2018

The Chemical Record

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Separability-based selection of cost-effective control of multistep processes in limited time and money

Fayzullaev

Tashmatova

Kurbanova

2021

J. Phys.: Conf. Ser.

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Modeling as a research method usually consists not in the preparation of proposals and the formation of technical requirements in the created sample, but at the stages of conceptual and technical design, in the development of product samples in systems using them, as well as in various tests. This article discusses optimal control of multi-step processes. Usually, in practice, the problem of constructing models of multistage processes, as a rule, is complicated by the universality, uncertainty and nonlinearity of the simulated objects, complete or partial lack of expert experience and analytical description of dependencies. Mathematical models describing chemical technology consider the partitioning of the state into discrete stages.

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Cost-effective electrosynthesis of a series of edaravones through an electrochemical-assisted domino heteroannulation and paired electrochemical process

Cited by 2 publications

References 38 publications

Electrochemically Induced Michael Addition Reaction: An Overview

Electrochemically Induced Michael Addition Reaction: An Overview

Separability-based selection of cost-effective control of multistep processes in limited time and money

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