By accelerated tests and electrochemical measurements, the characteristic of four selfassembled monolayer (SAM) covered silver, which were octadecanethiol monolayer from aqueous solution (OSA), octadecanethiol monolayer from organic solvent (OSO), phytic acid monolayer (IP 6 ) and silicon tungstemic acid monolayer (STA), was studied. The results indicated that the OSA, STA, IP 6 and OSO on the silver provided a practical method to prevent silver from tarnishing. All SAMs acted as cathodic inhibitors. The protection effect of OSA was similar to that of OSO, both of which were more effective than IP 6 and STA. The charge transfer resistance increased from 76 V cm 2 for bare silver up to 1456, 474 , 1050 and 1212 V cm 2 for OSA, STA, IP 6 and OSO covered silver respectively. The 48 h accelerated tarnishing tests proved the protection efficient of SAMs, in the order OSA