Correlation of lifetimes observed in two vibrational levels of the Σ state

Kiyoshima, Tatsuro; Sato, S.

doi:10.1016/s0009-2614(01)00612-1

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“…The fluorescence signal was first observed from a vibrationally excited v = 2 state of the E,F state, and its radiative lifetime was shown to be 100 ns [4]. Fluorescence from other vibrational states were also observed, and dependence of the radiative lifetime on the internal state was compared with theory [11][12][13].…”

Section: Introductionmentioning

confidence: 99%

Laser-induced fluorescence of hydrogen via the E,F1Σg+→B
Niki
¹
,
Fujiwara
²
,
Motoshima
³

et al. 2011
Chemical Physics Letters
5
0
3
0
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Section: Introductionmentioning

confidence: 99%

Laser-induced fluorescence of hydrogen via the E,F1Σg+→B
Niki
¹
,
Fujiwara
²
,
Motoshima
³

et al. 2011
Chemical Physics Letters
5
0
3
0
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Lifetimes of Vibro-Rotational Levels in Excited Electronic States of Diatomic Hydrogen Isotopologues

Astashkevich

Lavrov

2015

Journal of Physical and Chemical Reference Data

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Current situation in studies of lifetimes of excited rovibronic levels for the H 2 , D 2 , T 2 , HD, HT, and DT molecules is analyzed. All measured values of the lifetimes, reported before November 2014, are compiled and listed in the tabular format together with annotated bibliography. Experimental data are now available for the H 2 , HD and D 2 molecules only. The data collected in the present work show fragmentariness of experimental data. For vast majority of the levels the lifetime value was reported in one paper only, and has no independent experimental verification. Complete bibliography of publications concerning semi-empirical determination and non-empirical calculations of the lifetimes is presented. Numerical results obtained by these two approaches are listed in an explicit form only in the cases when experimental data are available. For more than half of the levels the differences between measured and calculated values are 3 times higher than experimental errors. This direct contradiction shows necessity of more precise experimental and non-empirical studies. For finite number of rovibronic levels our analysis made it possible to propose certain set of recommended data.

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General complex rotated finite-element method for predissociation studies of diatomic molecules: An application on the(1–6)Σg+1states

Andersson¹,

Elander²

2004

Phys. Rev. A

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Correlation of lifetimes observed in two vibrational levels of the Σ state

Cited by 3 publications

References 14 publications

Laser-induced fluorescence of hydrogen via the E,F1Σg+→B
Niki
¹
,
Fujiwara
²
,
Motoshima
³

et al. 2011
Chemical Physics Letters
5
0
3
0
View full text Add to dashboard Cite

Laser-induced fluorescence of hydrogen via the E,F1Σg+→B
Niki
¹
,
Fujiwara
²
,
Motoshima
³

et al. 2011
Chemical Physics Letters
5
0
3
0
View full text Add to dashboard Cite

Lifetimes of Vibro-Rotational Levels in Excited Electronic States of Diatomic Hydrogen Isotopologues

General complex rotated finite-element method for predissociation studies of diatomic molecules: An application on the(1–6)Σg+1states

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Correlation of lifetimes observed in two vibrational levels of the Σ state

Cited by 3 publications

References 14 publications

Laser-induced fluorescence of hydrogen via the E,F1Σg+→BNiki1, Fujiwara2, Motoshima3 et al. 2011Chemical Physics Letters5030View full textAdd to dashboardCite

Laser-induced fluorescence of hydrogen via the E,F1Σg+→BNiki1, Fujiwara2, Motoshima3 et al. 2011Chemical Physics Letters5030View full textAdd to dashboardCite

Lifetimes of Vibro-Rotational Levels in Excited Electronic States of Diatomic Hydrogen Isotopologues

General complex rotated finite-element method for predissociation studies of diatomic molecules: An application on the(1–6)Σg+1states

Contact Info

Product

Resources

About

Laser-induced fluorescence of hydrogen via the E,F1Σg+→B
Niki
¹
,
Fujiwara
²
,
Motoshima
³

et al. 2011
Chemical Physics Letters
5
0
3
0
View full text Add to dashboard Cite

Laser-induced fluorescence of hydrogen via the E,F1Σg+→B
Niki
¹
,
Fujiwara
²
,
Motoshima
³

et al. 2011
Chemical Physics Letters
5
0
3
0
View full text Add to dashboard Cite