The tendency of halogen-containing polymers to lose a part of their halogen through the catalytic action of light, heat, or chemical reagents has long been recognized. The changes in color and mechanical properties accompanying this degradation reaction were almost sufficient in the early days to militate against the use of such polymers.However, technological advances resulting from better control of the purity of raw materials, improved techniques of fabrication, and the employment of special light-and heat-stabilizing agents have so improved the situation that this problem is now mainly one of academic interest (28). And in proportion, as the practical aspects of the problem were solved, the academic side of the problem received more and more emphasis.