“…However, they are known to be highly toxic with foul‐smelling odor and this impedes its functionality. In stark contrast, the use of simple, bench‐stable and odorless electrophilic thiosulfonates for the formation of C−S bonds continues to be underdeveloped [5a–c,e,g, 6] . Cross‐electrophile couplings have surfaced as an impressive alternative to conventional cross‐couplings with preformed nucleophiles, providing an advantage in terms of step‐economy [7] .…”