Copper borate (CuB4O7)-promoted multi-component green synthesis of 2,4,5-triarylimidazole derivatives and evidence of in situ conversion of copper borate (CuB4O7) into Cu(OAc)2 in the presence of NH4OAc

Chettri, Sailesh; Tamang, Sumiran; Pradhan, Kiran; Sinha, Biswajit; Brahman, Dhiraj

doi:10.1039/d3ra03183g

RSC Adv.

2023

DOI: 10.1039/d3ra03183g

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Copper borate (CuB₄O₇)-promoted multi-component green synthesis of 2,4,5-triarylimidazole derivatives and evidence of in situ conversion of copper borate (CuB₄O₇) into Cu(OAc)₂ in the presence of NH₄OAc

Sailesh Chettri¹,

Sumiran Tamang²,

Kiran Pradhan

et al.

Abstract: A green, efficient, and straightforward methodology for the three-component synthesis of 2,4,5-triarylimidazole has been developed under solvent-free conditions using unconventional CuB4O7 as a promoter.

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The Chemistry of Aldehydes and Ketones in the Synthesis of Heterocycles - Historical Reactions with a New and Green Perspective

da Silva,

Junior,

Hernández Muñoz

2024

COC

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The reactivity of aldehydes and ketones carries great potential for multicomponent heterocyclizations. These reactions are convergent and highly versatile in the development of synthetic methodologies for compound families, displaying variations in substituents in their structures. Therefore, they have been regarded as an important tool in the field of Green Chemistry. Furthermore, they prove to be very useful in studies of biological activity, where small structural modifications can result in significant differences. Many heterocyclizations date back to the mid-19th and early 20th centuries. In this review, we aim to demonstrate, through some of these reactions, their continuously growing potential and improvements concerning synthetic development. Additionally, we present the original studies as reported, enabling us to appreciate the evolution of chemical representations over the years until reaching the standardization we have today.

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The Chemistry of Aldehydes and Ketones in the Synthesis of Heterocycles - Historical Reactions with a New and Green Perspective

da Silva,

Junior,

Hernández Muñoz

2024

COC

View full text Add to dashboard Cite

show abstract

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Copper borate (CuB₄O₇)-promoted multi-component green synthesis of 2,4,5-triarylimidazole derivatives and evidence of in situ conversion of copper borate (CuB₄O₇) into Cu(OAc)₂ in the presence of NH₄OAc

Abstract: A green, efficient, and straightforward methodology for the three-component synthesis of 2,4,5-triarylimidazole has been developed under solvent-free conditions using unconventional CuB4O7 as a promoter.

Cited by 1 publication

References 97 publications

The Chemistry of Aldehydes and Ketones in the Synthesis of Heterocycles - Historical Reactions with a New and Green Perspective

The Chemistry of Aldehydes and Ketones in the Synthesis of Heterocycles - Historical Reactions with a New and Green Perspective

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