Coordination polymers, 4. Electrical properties of some bisphenolic chelate polymers

Abstract

The electrical properties of Ni(I1) and Cu(I1) chelate polymers of bis(2,4-dihydroxybenzaldehyde), bis(2,4dihydroxyacetophenone), bis(2,4dihydroxybenzophenone), bis(2,4-dihydroxybenzaldehyde)ethylenediimine, bis(2,4-dihydroxyacetophenone)ethylenediimine, bis(2,4-dihydroxybenzophenone)ethylenediimine and bis(2,4-dihydroxyacetophenoneimine) and aromatic acid chlorides have been studied. The chelate polymers with the most rigid structure were found to have the highest conductivities. ZUS AMMENFASSUNG: Die elektrischen Eigenschaften von polymeren Ni(I1)-und Cu(I1)-Chelaten aus Bis(2,4-dihydroxybenzaldehyd), Bis(2,4-dihydroxyacetophenon), Bis(2,Cdihydroxybenzophenon), Bis(2,4-dihydroxybenzaldehyd)ethylendiimin, Bis(2,Cdihydroxyacetophenon)ethylendiimin, Bis(2,4-dihydroxybenzophenon)ethylendiimin und Bis(2,4-dihydroxyacetophenonimin) und aromatischen Saurechloriden wurden untersucht. Es wurde beobachtet, dal3 die polymeren Chelate mit der starrsten Struktur die hochsten Leitfahigkeiten besitzen. 0 1982 Hiithig & Wepf Verlag, Basel

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