Coördination Compounds of Boron Trichloride. I. A Review.

Coordination Compounds of Boron Fluoride

“…Later data of Martin and collaborators [54,61], however, confirm that BF 3 and P H 3 at a temperature of -50° form two coordination compounds P H 3 . BF 3 and P H 3 .…”

Coördination Compounds of Boron Trichloride. III. Systems with Methyl Chloride and Ethyl Chloride.

“…An apparatus suitable for the rapid measurement of the temperature coefficient of heterogeneous catalysis and thus of the activation energy and frequency factor has been developed in our laboratory during the last few years (8,9,10). Its principle is to distil the reactant over the catalyst, to condense…”

“…It has been demonstrated previously that the boron atom of boron trichloride acts as an acceptor atom in the formation of coordination compounds (8,9). There are only a few compounds of chlorine which coordinate with boron trichloride.…”

Novel Bonding Mode in Phosphine Haloboranes

“…The elucidation of the properties of boron- and phosphorous-based adducts has been of interest to chemists for many decades. − These compounds play many important roles in synthetic chemistry and are high-potential candidate materials for hydrogen storage. − Furthermore, B–P compounds are particularly known as efficient refractory semiconductor materials and thus are also of interest in solid-state physics and have shown potential as reducing agents in biological systems. , The importance of B–P complexes in a wide range of applications makes it critical to fully understand their structure and stability, which has been attempted both theoretically and experimentally dating back as far as the 1940s. − ,− …”