Articles you may be interested inSurface templates fabricated using a focused ion beam for lateral positioning of nanoscale islands on Si (001) substrates J.In this study, we use 25 keV in situ and 30 keV ex situ Ga + focused ion beams ͑FIBs͒ to locally modify the substrate before deposition and determine their effects on nucleation of molecular beam epitaxy grown Ge/ Si islands. FIB processing may alter island formation in at least five ways: the surfactant effect of Ga + , doping effects of subsurface Ga + , local strains, crystalline damage, and surface roughening. To explore these possibilities, we milled square regions of increasing Ga + doses and used atomic force microscopy to monitor islanding in and around these regions. For in situ experiments, doses ranged from ϳ10 13 to 5 ϫ 10 17 ions/ cm 2 ͑0.04-400 ML͒. We began to observe changes in island topology at doses as low as ϳ10 14 ions/ cm 2 . For doses of ϳ10 15 to ϳ8 ϫ 10 16 ions/ cm 2 ͑2-160 ML͒, implanted areas were surrounded by denuded zones that grew from ϳ0.5 to 6 m with increasing dose. Immediately inside the implanted area, island size and concentration appeared to peak. At doses above ϳ6 ϫ 10 16 ions/ cm 2 ͑120 ML͒, Ga + produced noticeable surface depressions, which were often surrounded by enhanced island densities, rather than a denuded zone. For ex situ FIB patterning, samples underwent both pregrowth cleaning and growth of a thin capping layer ͑0-100 nm͒. Doses ranging from 7.5ϫ 10 13 to ϳ10 17 ions/ cm 2 ͑0.15-200 ML͒ were used in concert with varied capping layer thicknesses to study their combined affect on island nucleation. The results correspond well with in situ experiments for thin capping layers. Increased capping layer thickness resulted in muted modifications to island formation for low Ga + doses, while for higher doses trends similar to those obtained in situ are seen.