Control of intramolecular .beta.-hydrogen migration in coordinatively unsaturated (diphosphine)platinum ethyl cations

Nucleophilic Attack of Amides onto Coordinated Ethylene in Platinum Complexes Supported by a Chelating Pyridyl−Pyrrolide Ligand: Azaplatinacyclobutane and Vinylamine Complexes

“…The solvent was removed in vacuo, and the resulting solid was washed with 5 mL of hexanes to give a yellow-orange powder in 70% yield (0.338 g, 0.620 mmol). 1 H NMR (C 6 D 6 ): 28. The combustion analysis gave essentially the same results after recrystallization from THF, despite the lack of NMR signals due to impurities in this sample.…”

Platinum organometallic compounds: classification and analysis of crystallographic and structural data. Part I. Monomeric Pt(0) and partly of Pt(II) with PtC4, PtA3B and PtC2A2 chromophores

“…There are 68 examples (Bombieri et al 1970, Pannatoni et al 1970, Kadonaga et al 1971, Albano et al 1972, Cheng and Nyburg 1972, Baraban and McGinnety 1974, 1975, Browning and Penfold 1974, Davies and Payne 1974, 1975, Jason et al 1974, de Boer and Bright 1975, Jason and McGinnety 1975, Robertson and Whimp 1975, Yasuoka et al 1975, Jagner et al 1976, Richardson and Payne 1977, Barker et al 1978, Cobbledick and Einstein 1978, Lenarda et al 1978, Manojlovic -Muir et al 1979, Stamm et al 1979, Robertson and Whimp 1980, Farrar and Payne 1981a, Osborne et al 1981, Christofi des et al 1982, Osborne and Ibers 1982, Winchester et al 1985, Ferguson et al 1987, Philips et al 1987, Sen et al 1987, Clark et al 1988, Packelt et al 1988, Camalli et al 1990, Kumar et al 1990, Rheingold et al 1990, Carr et al 1991, Caruso et al 1991, Choi et al 1991, Fagan et al 1991…”

Bis(tert‐butylimido)‐bis(dialkylamido) Complexes of Molybdenum as Atomic Layer Deposition (ALD) Precursors for Molybdenum Nitride: the Effect of the Alkyl Group

“…The migrations of b-hydrogen and b-methyl are common decomposition pathways for organometallic complexes. [27][28][29] More specifically, for alkylamido complexes, metallacycle formation reactions have been recognized. [30][31][32][33] These reactions were applied as possible decomposition reaction pathways for 1-3.…”

“…200706668 Full Paper common decomposition pathway for organometallic complexes. [27][28][29] Also, typically for dialkylamido complexes, decomposition occurs via b-H abstraction and dialkylamine elimination, so that a metal-nitrogen-carbon -three membered ring, a metallacycle, is formed. Metallacycles has been observed, for example, for tetrakis(dimethylamido)titanium and for bis(tert-butylimido)-bis(diethylamido)tungsten during thermolysis in the gas phase.…”