The mixed spin-(1/2, SB, SC) Ising model on a decorated square lattice with two different kinds of decorating spins SB and SC (SB = SC) placed on its horizontal and vertical bonds, respectively, is exactly solved by establishing a precise mapping relationship with the corresponding spin-1/2 Ising model on an anisotropic square (rectangular) lattice. The effect of uniaxial single-ion anisotropy acting on both types of decorating spins SB and SC is examined in particular. If decorating spins SB and SC are integer and half-odd-integer, respectively, or if the reverse is the case, the model under investigation displays a very peculiar critical behavior beared on the spontaneously ordered 'quasi-1D' spin system, which appears as a result of the single-ion anisotropy strengthening. We have found convincing evidence that this remarkable spontaneous ordering virtually arises even though all integer-valued decorating spins tend towards their 'non-magnetic' spin state S = 0 and the system becomes disordered only upon further increase of the single-ion anisotropy. The single-ion anisotropy parameter is also at an origin of various temperature dependences of the total magnetization when imposing the pure ferrimagnetic or the mixed ferro-ferrimagnetic character of the spin arrangement.