Construction of Mechanically Reinforced Thermoplastic Polyurethane from Carbon Dioxide-Based Poly(ether carbonate) Polyols via Coordination Cross-Linking

Abstract

Using carbon dioxide-based poly(propylene ether carbonate) diol (PPCD), isophorone diisocyanate (IPDI), dimethylolbutyric acid (DMBA), ferric chloride (FeCl3), and ethylene glycol (EG) as the main raw materials, a novel thermoplastic polyurethane (TPU) is prepared through coordination of FeCl3 and DMBA to obtain TPU containing coordination enhancement directly. The Fourier transform infrared spectroscopy, 1H NMR, gel permeation chromatography, UV−Vis spectroscopy, tensile testing, dynamic mechanical analysis, X-ray diffraction, differential scanning calorimetry, and thermogravimetric analysis were explored to characterize chemical structures and mechanical properties of as-prepared TPU. With the increasing addition of FeCl3, the tensile strength and modulus of TPU increase. Although the elongation at break decreases, it still maintains a high level. Dynamic mechanical analysis shows that the glass-transition temperature moves to a high temperature gradually along with the increasing addition of FeCl3. X-ray diffraction results indicate that TPUs reinforced with FeCl3 or not are amorphous polymers. That FeCl3 coordinates with DMBA first is an effective strategy of getting TPU, which is effective and convenient in the industry without the separation of intermediate products. This work confirms that such Lewis acids as FeCl3 can improve and adjust the properties of TPU contenting coordination structures with an in-situ reaction in a low addition amount, which expands their applications in industry and engineering areas.

Synthesis of PPC-graft-poly(PEOMA) Brush and PPC Gels via Post-polymerization Modification of Hydroxyl-Functionalized Poly(propylene carbonate)

“…Poly (propylene carbonate) (PPC) is an ecofriendly biodegradable polymer synthesized from carbon dioxide (CO 2 ) and propylene oxide (PO) [1,2]. In consideration of largely available "greenhouse" gas CO 2 can be utilized as a cheap carbon resource for PPC production, this copolymer has gained a continuous interest worldwide in the elds of academia and industry [3][4][5]. As a thermoplastic aliphatic polycarbonate, PPC has the properties of desirable biodegradability, good biocompatibility, excellent oxygen barrier performance and su cient toughness at ambient temperature, which has potential applications in packaging, adhesives, biomedical material, etc [6][7][8].…”