Dissociative dynamics of the K shell excited ozone has been investigated by time-of-flight (TOF) mass spectra of fragment ions for the first time. The TOF spectra were acquired at 0 and 90°relative to the electric vector of linearly polarized soft X-ray. In the K shell excitation at the 529 eV photoabsorption peak, the energetic O + fragment ion was ejected anisotropically, while at the 536 eV band it was isotropic. The β values calculated from simulation of the TOF spectra are consistent with the previous assignments that the 529 eV band is the π* r O T (1s) resonance excitation and that the 536 eV band mainly consists of two transitions, π*(2b 1 ) r O C (1s) and σ*(7a 1 ) r O T (1s) [Gejo et al. Chem. Phys. Lett. 277 (1997) 497]. The TOF spectra show that the π* excitation of terminal oxygen atoms generates more O 2 + fragment than the excitation of the center oxygen atom.