We study Fermi liquid instabilities in spin-orbit-coupled metals with inversion symmetry. By introducing a canonical basis for the doubly degenerate Bloch bands in momentum space, we derive the general form of Landau interaction functions. A variety of time-reversal-invariant, parity-breaking phases is found, whose Fermi surface is spontaneously deformed and spin split. In terms of symmetry, these phases possess gyrotropic, ferroelectric, and multipolar orders. The ferroelectric and multipolar phases are accompanied by structural distortions, from which the electronic orders can be identified. The gyrotropic phase exhibits a unique nonlinear optical property. We identify correlated electron materials that exhibit these parity-breaking phases, including Novel physics from strong spin-orbit coupling in quantum materials is currently attracting widespread interest across many disciplines in condensed matter physics. In particular, there is now an intensive investigation of the interplay between spin-orbit coupling and electron correlation in d-orbital and f-orbital systems [1][2][3]. The majority of studies have been focused on correlated band or Mott insulators, whereas spin-orbit coupling in correlated metals has received less attention. It is well known that spin-orbit coupling in metals without inversion symmetry generates spin-split energy bands and spin-polarized Fermi surfaces [4]. This has interesting consequences in the presence of electron-electron interactions [5][6][7][8][9][10][11]. In contrast, in metals with inversion and time-reversal symmetry, Bloch bands are doubly degenerate everywhere in momentum space. The effect of spin-orbit coupling is more subtle: it leads to spin-orbit-entangled Bloch wave functions, which have different spin polarizations on different atomic orbitals [12,13]. For this reason, the importance of spin-orbit coupling in inversion-symmetric materials can be easily overlooked.In this Letter, we explore the consequences of having both strong spin-orbit coupling and electron interaction in metals with inversion symmetry. By generalizing Landau's Fermi liquid theory to spin-orbit-coupled metals, we theoretically predict a variety of new ordered phases resulting from Pomeranchuk-type instabilities in the spin channel [14], which spontaneously break inversion symmetry. These phases can be regarded as new examples of electronic liquid crystals [15], which preserve the translational invariance and break the point group symmetry of the lattice. Importantly, because of the spin-orbit coupling, these phases exhibit spin-split Fermi surfaces with characteristic spin textures, and the onset of electronic paritybreaking orders is generally accompanied by structural changes. We focus on three different parity-breaking phases having the symmetry of ferroelectric, a multipolar and an isotropic gyrotropic liquid, respectively, and identify their realizations in correlated electron materials.Landau's Fermi liquid theory of metals starts from Bloch states on the Fermi surface. In the presence of ...