Carbon nanotubes are considered short fibers, and polymer composites with nanotube fillers are always analogues of random, short fiber composites. The real structural carbon fiber composites, on the other hand, always contain carbon fiber reinforcements where fibers run continuously through the composite matrix. With the recent optimization in aligned nanotube growth, samples of nanotubes in macroscopic lengths have become available, and this allows the creation of composites that are similar to the continuous fiber composites with individual nanotubes running continuously through the composite body. This allows the proper utilization of the extreme high modulus and strength predicted for nanotubes in structural composites. Here, we fabricate such continuous nanotube polymer composites with continuous nanotube reinforcements and report that under compressive loadings, the nanotube composites can generate more than an order of magnitude improvement in the longitudinal modulus (up to 3,300%) as well as damping capability (up to 2,100%). It is also observed that composites with a random distribution of nanotubes of same length and similar filler fraction provide three times less effective reinforcement in composites.
The spin-1=2 triangular lattice antiferromagnet YbMgGaO 4 has attracted attention recently as a quantum spin-liquid candidate with the possible presence of off-diagonal anisotropic exchange interactions induced by spin-orbit coupling. Whether a quantum spin liquid is stabilized or not depends on the interplay of various exchange interactions with chemical disorder that is inherent to the layered structure of the compound. We combine time-domain terahertz spectroscopy and inelastic neutron scattering measurements in the field-polarized state of YbMgGaO 4 to obtain better insight of its exchange interactions. Terahertz spectroscopy in this fashion functions as a high-field electron spin resonance and probes the spin-wave excitations at the Brillouin zone center, ideally complementing neutron scattering. A global spin-wave fit to all our spectroscopic data at fields over 4 T, informed by the analysis of the terahertz spectroscopy linewidths, yields constraints on the disorder-averaged g factors and exchange interactions. Our results paint YbMgGaO 4 as an easy-plane XXZ antiferromagnet with the combined and necessary presence of subleading next-nearest neighbor and weak anisotropic off-diagonal nearest-neighbor interactions. Moreover, the obtained g factors are substantially different from previous reports. This work establishes the hierarchy of exchange interactions in YbMgGaO 4 from high-field data alone and thus strongly constrains possible mechanisms responsible for the observed spin-liquid phenomenology.
Antiadhesion barriers such as films and hydrogels used to wrap repaired tendons are important for preventing the formation of adhesion tissue after tendon surgery. However, sliding of the tendon can compress the adjacent hydrogel barrier and cause it to rupture, which may then lead to unexpected inflammation. Here, a self‐healing and deformable hyaluronic acid (HA) hydrogel is constructed as a peritendinous antiadhesion barrier. Matrix metalloproteinase‐2 (MMP‐2)‐degradable gelatin‐methacryloyl (GelMA) microspheres (MSs) encapsulated with Smad3‐siRNA nanoparticles are entrapped within the HA hydrogel to inhibit fibroblast proliferation and prevent peritendinous adhesion. GelMA MSs are responsively degraded by upregulation of MMP‐2, achieving on‐demand release of siRNA nanoparticles. Silencing effect of Smad3‐siRNA nanoparticles is around 75% toward targeted gene. Furthermore, the self‐healing hydrogel shows relatively attenuated inflammation compared to non‐healing hydrogel. The mean adhesion scores of composite barrier group are 1.67 ± 0.51 and 2.17 ± 0.75 by macroscopic and histological evaluation, respectively. The proposed self‐healing hydrogel antiadhesion barrier with MMP‐2‐responsive drug release behavior is highly effective for decreasing inflammation and inhibiting tendon adhesion. Therefore, this research provides a new strategy for the development of safe and effective antiadhesion barriers.
Reliable experimental models are needed to help improve our knowledge of how the central nervous system adapts to function in the presence of muscle pain in man. We developed a microprocessor-based control system for maintaining a constant level of experimental muscle pain. Pain was induced in the relaxed right masseter of healthy young adults by using an infusion pump to inject an algesic 0.15 mL bolus of 5% hypertonic saline over 15 s. Subjects supplied feedback on their present pain intensity (PPI) via a 10 cm long electronic visual-analog scale (VAS) and a 0.07 Hz zero-order hold. The adaptive controller identified the system dynamic response and proportional-integral-derivative (PID) controller parameters from the subject's initial response to the bolus (pain rise and fall time constants and peak amplitude) as well as his/her response to a 90 s constant infusion. Finally, using the pain feedback the adaptive PID controller was successfully used to adjust the infusion rate to maintain PPI in five out of seven healthy adults at a mean (SD) 4.8(0.9) PPI level with respect to the 5.0 PPI setpoint for periods up to 15 min (when the experiment was arbitrarily terminated). The infusion rate required to maintain the given level of masseter pain was found to increase by approximately 3 to 5%/minute.
The CLVQOL Chinese is a culturally specific vision-related quality-of-life measure instrument. It satisfies conventional psychometric criteria, discriminates visually healthy populations from low vision patients and may be valuable in screening the local community as well as for use in clinical practice or research.
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