Conjugate addition reactions of metallated alkyl pyridines. A direct route to 6-substituted pyridones

Kraus, George A.; Vines, D. R.; Malpert, John H.

doi:10.1016/0040-4020(94)01020-z

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Pest-control Agents Have Attracted Attention (R)-( +)-1

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Cited by 6 publications

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“…Simultaneous desulfurisation and debenzylation using RaNi leads to the pyridone 298. 463 The keto silane 299 is reduced by Li-NH, to give the hydroxy silane 300 which reacts with Bu4NF followed by H202 to give the diol 301 with retention of stereochemistry at the C-Si centre. 464 The latter steps of the sequence provide a method for the conversion of a silane into an alcohol in the presence of an olefinic bond.…”

Section: Pest-control Agents Have Attracted Attention (R)-( +)-mentioning

confidence: 99%

Monoterpenoids

Grayson¹

1997

Nat. Prod. Rep.

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Section: Pest-control Agents Have Attracted Attention (R)-( +)-mentioning

confidence: 99%

Monoterpenoids

Grayson¹

1997

Nat. Prod. Rep.

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ChemInform Abstract: Conjugate Addition Reactions of Metalated Alkyl Pyridines. A Direct Route to 6‐Substituted Pyridones.

1995

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Conjugate Addition Reactions of Metalated Alkyl Pyridines. A Direct Route to 6-Substituted Pyridones.-The reaction of metalated alkyl pyridines with α,β-unsaturated ketones yields 1,2-and/or 1,4-addition products. Deprotection of (VII) using fresh prepared Raney-Ni results in formation of the pyridone (IX), a type of compound required as structural subunit in many biologically active compounds. -(KRAUS, G. A.; VINES, D. R.; MALPERT, J. H.; Tetrahedron 51 (1995) 5, 1337-1344; Dep. Chem., Iowa State Univ., Ames, IA 50011, USA; EN)

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One or More CH Bond(s) Formed by Substitution: Reduction of CHalogen and CChalcogen Bonds

Sutherland¹

2005

Comprehensive Organic Functional Group Transformations II

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Conjugate addition reactions of metallated alkyl pyridines. A direct route to 6-substituted pyridones

Cited by 6 publications

References 9 publications

Monoterpenoids

Monoterpenoids

ChemInform Abstract: Conjugate Addition Reactions of Metalated Alkyl Pyridines. A Direct Route to 6‐Substituted Pyridones.

One or More CH Bond(s) Formed by Substitution: Reduction of CHalogen and CChalcogen Bonds

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