2017
DOI: 10.1016/j.cplett.2017.01.068
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Conformer-specific geminate recombination following methyl nitrite photolysis in solution

Abstract: General rightsThis document is made available in accordance with publisher policies. Please cite only the published version using the reference above. Full terms of use are available: http://www.bristol.ac.uk/pure/about/ebr-terms UV excitation in the structured S1  S0 absorption band induces dissociation, with geminate recombination and vibrational cooling of syn and anti-conformers of methyl nitrate on a timescale of ~56 ps. Solvent-induced vibrational cooling favours relaxation to the higher-energy anti-con… Show more

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