“…33 Recently, a similar strategy has been applied to the LIBS, which signicantly enhances the signal-to-noise ratio during the long-term measurement. 34,35 In this paper, we propose a confocal microscopy-controlled Raman-LIBS hybrid method with high spatial resolution and stability. The confocal system, depending on the Rayleigh/ reected light, is described as confocal controlled microscopy, which measures surface topography and achieves highprecision axial focusing, enabling long-time threedimensional (3D) spectral mapping of the sample.…”