2011
DOI: 10.1002/macp.201100395
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Conductive Polymer for Elevated Temperature Applications Based on Sodium Sulfosuccinate Coupled Poly(ethylene glycol)s

Abstract: Sodium sulfosuccinate coupled poly(ethylene glycol) (PEG) (S–PEG–SS) conductive polymers for hot melt adhesives are synthesized from PEG, maleic anhydride, and sodium hydrogen sulphite using a one‐pot three‐step reaction. Infrared spectroscopy and 1H NMR spectroscopy are used to characterize the molecular structure and to determine the yield of esterification. S–PEG150–SS has the highest yield of esterification, whereas S–PEG2000–SS provides the lowest yield of esterification. Gel permeation chromatography and… Show more

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Cited by 2 publications
(2 citation statements)
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References 27 publications
(22 reference statements)
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“…The degree of polymerization was similar for polyesters with OEG having M n ≤ 400 and started to decrease when OEG's M n ≥ 1000. The decrease in polyester M w with increasing glycol molecular weight has previously been found for other polyesters based on polyethylene glycols . The highest molar mass in this series obtained for DCA‐OEG600 (about 20 000) was probably due to better solubility of the monomers in the polycondensation medium.…”
Section: Resultssupporting
confidence: 76%
“…The degree of polymerization was similar for polyesters with OEG having M n ≤ 400 and started to decrease when OEG's M n ≥ 1000. The decrease in polyester M w with increasing glycol molecular weight has previously been found for other polyesters based on polyethylene glycols . The highest molar mass in this series obtained for DCA‐OEG600 (about 20 000) was probably due to better solubility of the monomers in the polycondensation medium.…”
Section: Resultssupporting
confidence: 76%
“…They reported a conductivity of 5 × 10 5 S/m and observed that increasing the temperature helped to form necks between particles and improved the conductivity. For their part, Zimmerer et al93 developed a conductive additive based on an intrinsically conductive polymer [sodium sulfosuccianate coupled poly(ethylene glycol)] for hot‐melt adhesives. The highest obtained conductivity was 0.9 S/m, which according to the authors, was useful for hot‐melt adhesives and for antistatic plastic coatings.…”
Section: Ecas That Do Not Cure: Hot‐melt Adhesives and Psasmentioning
confidence: 99%