As is known, metal−organic frameworks (MOFs) are a versatile class of materials in energy storage applications including supercapacitors. However, the individual kind of metal nodes connected by organic ligands to form a topological structure still limits the potential storage capacity of MOFs. Herein, a bimetal-based Ni−Mn MOF composite is configured with a onepot hydrothermal method to derive a composite with a synergic effect to maximize the properties. Moreover, reduced graphene oxide (rGO) sheets are added as a conductive network to anchor the MOF-derived composite of Ni−Mn@C/rGO, which is expected to increase the conductivity of the materials system. The resulting composite exhibited a high specific capacitance of 1674 F g −1 at a current density of 0.3 A g −1 , suggesting excellent energy storage performance. The composite was then integrated as the cathode in an asymmetrical supercapacitor with a 3D rGO aerogel anode, resulting in energy densities of 24.1 and 17.5 W h kg −1 at power densities of 88.9 and 444.4 W kg −1 , respectively. Additionally, the device demonstrated remarkable long-term stability, with 90% capacitance retention after 10 000 charge−discharge cycles at 10 A g −1 .